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バイオ燃料研究グループ

バイオ燃料研究グループは、化学と化学工学の知識を持つ4人の学生で構成され、廃棄物からバイオ燃料と有用な化学物質を作成するための基礎研究と応用プロセス工学研究の両方を
行っています。    

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Palladium Copper (PdCu) membrane-based hydrogen gas separation

Since 2021, the Cross lab has been undertaking hydrogen gas separation research using a Swagelok VCR based 20 cm diameter PdCu membranes of 10 and 15 microns thick, from Tanaka Kinzoku Ltd, Tokyo, Japan (see fig below.).
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Experiments have been done over a range of pressures and temperatures and PdCu membranes characterized to understand how the film crystallinity impacts hydrogen permittivity. The results have recently been submitted for publication in the International Journal of Hydrogen Energy. Current research is underway on separating hydrogen gas from a syngas mixture. 
In addition, the lab also has an Element 1 Corp (e1). hydrogen gas purifier (below) which is on loan from Element 1 Corp, Bend, Oregon. The purifier was developed over 30 years under the direction of Dr. David Edlund. The membrane-based purification module is at the core of e1’s protected intellectual property.  The proven and mature proprietary technology within the purification module is scalable, reliable and affordable for hydrogen purification and an alternative to micro-pressure swing absorption (PSA). The e1 purifier has been installed in a ceramic furnace.
Ref. https://www.environmental-expert.com/products/element-1-hydrogen-purifier-module-678895
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Muhammad Harussani Moklis (M. M. Harussani)

IGP-C (MEXT Scholarship), Energy Course, D3 student

Glycerol upgrading via electrocatalytic reduction assisted with machine learning (ML)

Japan is advancing towards a biofuel-driven future, with biodiesel production, from 2013 to 2022, exceeding 124,000 kiloliters which is in line with their ambition for net-zero greenhouse gas emissions by 2050. However, the increase in biodiesel manufacturing will generate abundant crude glycerol by-products, constituting 10-20% of total production. Conventionally, this waste was purified at high costs, but electrochemical conversion technology presents a greener and more economical alternative valorization to be integrated into the energy system. Here, our study focuses on the electrocatalytic reduction (also called thermo-electrocatalytic deoxygenation) of glycerol into value-added products including propanediols, propanols, etc. Utilizing machine learning (ML), we aimed to control the reaction as well as discover novel low-cost electrocatalyst for enhanced product yields.
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Eric KOLOR

IGP-C (Japanese MEXT Scholarship), Energy Science and Informatics, D1 student

Machine learning  and DFT assisted screening of palladium-lean alloy membranes for hydrogen gas purification

Advanced computer modeling and laboratory experiments are utilized to find cheaper more effective metal alloys for pure hydrogen gas separation from gas mixtures. This will be accomplished by using multi-objective Bayesian optimization (MOBO) and a computational chemistry method known as density functional theory (DFT). Thin metal alloy membranes will separate hydrogen from other gases with a high throughput. This research is expected to produce high-purity, inexpensive hydrogen for use in fuel cells and for use hydrogen gas carriers

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Md. Rubel

IGP-A (MEXT Scholarship), Energy Course, D1 student

Sustainable Aviation Fuel (SAF) Synthesis Optimized by Employing Machine Learning from Waste Cooking Oil (WCO) via Tri-Metallic Catalytic Conversion

The high cost of Sustainable Aviation Fuel (SAF) compared to conventional jet fuels is due to expensive production, limited capacity, and uncertain feedstock availability, which are global and Japan-specific challenges for SAF production. To address these challenges, this research focuses on optimizing SAF production from waste cooking oil (WCO) by developing new technologies, such as more efficient catalysts. Noble metal catalysts are costly, and conventional transition metals require high temperatures, pressure, and long reaction times for WCO hydrogenation. This study proposes a new trimetallic catalyst, optimized with a machine learning (ML) approach, to achieve a high conversion rate and jet fuel selectivity in the Hydroprocessed Esters and Fatty Acids (HEFA) process. This approach could enhance SAF production more efficient, reduce dependency on fossil fuels, lower greenhouse gas (GHG) emissions, and support the aviation industry’s goal of achieving net-zero emissions by 2050.

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